Synthesis of (β-N-Sulfonylaminoalkyl)phosphines and Their Use in Palladium-Mediated Asymmetric Synthesis

Shunji SAKURABA; Toshimi OKADA; Toshiaki MORIMOTO; Kazuo ACHIWA

doi:10.1248/cpb.43.927

Chemical and Pharmaceutical Bulletin

Online ISSN : 1347-5223
Print ISSN : 0009-2363

Synthesis of (β-N-Sulfonylaminoalkyl)phosphines and Their Use in Palladium-Mediated Asymmetric Synthesis

Shunji SAKURABA, Toshimi OKADA, Toshiaki MORIMOTO, Kazuo ACHIWA

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Keywords: catalytic asymmetric hydrosilylation, catalytic asymmetric Heck-type hydroarylation, palladium complex, aminophosphine

JOURNALS FREE ACCESS

Volume 43 (1995) Issue 6 Pages 927-934

DOI https://doi.org/10.1248/cpb.43.927

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Abstract

A series of (β-N-sulfonylaminoalkyl)phosphine ligands has been developed and employed for asymmetric palladium-catalyzed hydrosilylation and Heck-type hydroarylation, affording up to 72% ee and 90% yield.

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