Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
REDUCTION OF DITHIOACETALS WITH SmI2 IN BENZENE-HMPA
Munetaka KUNISHIMADaisuke NAKATAKazuhito HIOKIShohei TANI
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Volume 46 (1998) Issue 1 Pages 187-189

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Abstract

Partial reduction of dithioacetals to the corresponding sulfides was effected by samarium iodide in the presence of either t-BuOH or acetic acid in benzene-HMPA. An α-sulfenyl anion was shown to be involved.

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