Ultrasonic Effects on Electroorganic Processes. Part 26. Current Efficiency and Product Selectivity in the Anodic Cyanation of N-Methylpyrrole

Mahito ATOBE; Takashi AOYAGI; Toshio FUCHIGAMI; Tsutomu NONAKA

doi:10.5796/electrochemistry.72.821

コミュニケーション

Ultrasonic Effects on Electroorganic Processes. Part 26. Current Efficiency and Product Selectivity in the Anodic Cyanation of N-Methylpyrrole

Mahito ATOBE, Takashi AOYAGI, Toshio FUCHIGAMI, Tsutomu NONAKA

著者情報

キーワード: Sonoelectrochemistry, Ultrasonication, Product Selectivity, Anodic Cyanation, N-Methylpyrrole

ジャーナルフリー

2004 年 72 巻 12 号 p. 821-823

DOI https://doi.org/10.5796/electrochemistry.72.821

詳細

抄録

Ultrasonic effect on the anodic cyanation of N-methylpyrrole was examined. Current efficiency and product selectivity for the monocyanated product formed by two-electrons oxidation along with dicyanated product formed by four-electrons oxidation, were significantly increased under ultrasonication. Moreover, it was also found that considerably high efficiency and selectivity could be obtained under ultrasonication even if the concentration of cyanide as a nucleophile was decreased. This is desirable from an environmental viewpoint.

責任著者(Corresponding author)

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