Electrochemistry
Online ISSN : 2186-2451
Print ISSN : 1344-3542
ISSN-L : 1344-3542
Articles
Fabrication and Efficiency Enhancement of Water-based Dye-Sensitized Solar Cells by Interfacial Activation of TiO2 Mesopores
Haruhisa SAITOSadao UEGUSATakurou N. MURAKAMINorimichi KAWASHIMATsutomu MIYASAKA
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2004 Volume 72 Issue 5 Pages 310-316

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Abstract

Dye-sensitized solar cells were fabricated by using water-based electrolytes for the purpose to realize environmentally benign, green solar cells in which electrolyte solvent, water, can serve as a recyclable medium. Mesoporous TiO2 electrode was treated with ozone and UV light for hydrophilic conversion of the TiO2 mesopore and was dyesensitized with Ru(bipy)2 (SCN)2 in the presence of 4-tert-butylpyridine. These processes for surface activation highly improved photocurrent density and voltage of the electrode in contact with aqueous electrolytes that contain iodide/iodine as redox agents. Replacement of a portion of water with ethanol in the electrolyte composition further enhanced photovoltaic performance. With aqueous electrolyte containing 35% ethanol, photocell achieved power conversion efficiency of 2.2% under exposure to simulated solar light of 100 mW/cm2.

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© 2004 The Electrochemical Society of Japan
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