Electrochemistry
Online ISSN : 2186-2451
Print ISSN : 1344-3542
ISSN-L : 1344-3542
Articles
The Performance of Active Carbon Adsorbed with Cu(II)-picolinic Acid Complex as Electric Double Layer Capacitor (part 2)
Shu-ichi SASAKISachio YOSHIHARA
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2009 Volume 77 Issue 4 Pages 315-318

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Abstract

We have already reported about the performance of active carbon adsorbed with Cu(II)-picolinic acid complex. The capacitor showed higher capacitance than normal activated carbon. In this report, we have used another kind of AC and electrolyte. We could observe it’s accurate oxidation-reduction reaction by cyclic voltammetry and constant current electrolysis. We also comfirmed Cu(II)-picolinic acid complex’s disorption from the AC in the 4 M H2SO4/H2O. The cause of disorption is form of Cu(II)-picolinic acid in the low pH. We change electrolyte into 3.5 M NaBr/H2O and the disorption is suppressed.

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© 2009 The Electrochemical Society of Japan
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