Electrochemistry
Online ISSN : 2186-2451
Print ISSN : 1344-3542
ISSN-L : 1344-3542
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Redox Equilibria of the U4+/U3+ and U3+/U Couples in Molten LiCl-RbCl Eutectic
Takayuki NAGAIAkihiro UEHARAToshiyuki FUJIIOsamu SHIRAINobuaki SATOHajimu YAMANA
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2009 年 77 巻 8 号 p. 614-616

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Formal redox potentials of the U4+/U3+ and U3+/U couples in molten LiCl-RbCl eutectic were determined by cyclic voltammetry. These redox potentials were more negative than those in the LiCl-KCl eutectic but positive comparing to those in the NaCl-CsCl eutectic. This relation would be correlated with the averaged alkali cation radius.

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© 2009 The Electrochemical Society of Japan
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