コミュニケーション
Electrochemical Modification of a Fluorene-Carbazole Alternating Copolymer toward a Novel Donor-Acceptor Type Conjugated Polymer
2010 年 78 巻 2 号 p. 114-117
詳細
2010 年 78 巻 2 号 p. 114-117
An electroactive polymer, poly[9,9-bis(p-isopropylphenylsulfanyl)fluorene-alt-N-decylcarbazole] (P2) was prepared. Electrochemical fluorodesulfurization was carried out using a P2-coated platinum anode. From 1H-NMR, EDX analyses, about 50% fluorodesulfurization at the 9-position of fluorene was confirmed. The UV-vis absorption spectra of the novel donor-acceptor copolymer containing n-type unit exhibited intramolecular charge transfer (ICT) character.
