Electrochemistry
Online ISSN : 2186-2451
Print ISSN : 1344-3542
ISSN-L : 1344-3542
Communication
Influence of Halide Species on Magnesium Deposition Properties in Electrolyte Containing Phenoxyimine–Magnesium Halide Complex
Minato EGASHIRAKaori HIRATSUKASatomi TAKAHARAKouki MATSUBARA
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JOURNALS OPEN ACCESS

2019 Volume 87 Issue 5 Pages 251-253

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Abstract

This study evaluated the influence of halide anion of phenoxyimine–magnesium halide complex on magnesium deposition–dissolution in Mg(TFSA)2/triglyme electrolyte containing the magnesium halide complex. The chloride complex provides rather high Coulombic efficiency of reversible magnesium deposition compared with bromide analogue. This difference appears to be in relation to the different complexation equilibrium by Mg2+, Cl, and solvent molecules.

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© 2019 The Electrochemical Society of Japan
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