Electrochemistry
Online ISSN : 2186-2451
Print ISSN : 1344-3542
ISSN-L : 1344-3542
Articles
Digital Holography Study of the Inhibitory Effects of Polyaspartic Acid on the Anodic Dissolution of Inconel® 600
Yu SHAOJiaojiao QIBoyu YUANLiang LIChao WANG
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JOURNALS OPEN ACCESS

2021 Volume 89 Issue 3 Pages 267-272

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Abstract

Electrochemical methods were used in conjunction with digital holography to study the effects of an environmentally friendly inhibitor, polyaspartic acid (PASP), on the anodic dissolution of Inconel® 600 in a 0.04 M HCl solution. The pitting inhibition ability was enhanced and the inhibition efficiency increased with the PASP concentration, reaching 84.13 % at 6.66 g L−1 PASP. A digital holograph was used to observe the in situ hydrolysis of M2+ (M = Ni and Fe) near the electrode surface during anodic dissolution and showed the formation of a surface film on the electrode. The inhibitory effects of PASP on Inconel® 600 may be caused by the adsorption of PASP and the formation of a PASP metal complex (PASP-M complex), which may seal defects in the surface film.

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© The Author(s) 2021. Published by ECSJ.

This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium provided the original work is properly cited. [DOI: 10.5796/electrochemistry.21-00021].
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