Electrochemistry
Online ISSN : 2186-2451
Print ISSN : 1344-3542
ISSN-L : 1344-3542
CORRECTED PROOF
Amorphous Li2O–LiI Solid Electrolytes Compatible to Li Metal
Yushi FUJITAYusuke KAWASAKITakeaki INAOKATakuya KIMURAAtsushi SAKUDAMasahiro TATSUMISAGOAkitoshi HAYASHI
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JOURNALS OPEN ACCESS Advance online publication

Article ID: 21-00049

CORRECTED PROOF: June 04, 2021
UNCORRECTED PROOF: May 21, 2021
ACCEPTED MANUSCRIPT: April 29, 2021
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Article 1st page
Abstract

Development of oxide solid electrolytes for all-solid-state batteries is attracting increasing attention. In this study, amorphous Li2O–LiI materials are prepared via a mechanochemical process to achieve high lithium ionic conductivity and good compatibility to lithium metal. Amorphous 66.7Li2O·33.3LiI (mol%) electrolyte shows a high ionic conductivity of 3.1 × 10−5 S cm−1 at 25 °C with a relative density of 96 %. An all-solid-state Li symmetric cell (Li/66.7Li2O·33.3LiI/Li) operates without an increase in overvoltage. A simple combination of lithium oxide and lithium iodide exhibits high ionic conductivity, ductility, and stability to lithium metal.

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© The Author(s) 2021. Published by ECSJ.

This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium provided the original work is properly cited. [DOI: 10.5796/electrochemistry.21-00049].
http://creativecommons.org/licenses/by/4.0/
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