Proceedings of the Symposium on Progress in Organic Reactions and Syntheses
31th Synposium on Progress in Organic Reactions and Syntheses
Session ID : 1P-25
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Host: Division of Organic Chemistry, The Pharmaceutical Society of Japan

Development of photocleavable molecular devices for laser ionization
*Koji Ishida, Toshihide Maki
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Keywords: Photocleavable molecule, Laser ionization, TOF-Mass, linker
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Abstract

A new type of photocleavable molecular devices has been developed for laser ionization TOF-Mass spectrometry. The presented molecules contain an ether bond which is photo cleavable. Highly selective photo cleavage of the ether bond was observed under standard laser ionization condition by negative mode TOF-Mass spectrometry. The observed result indicates that chemically robust ether bond can be used as photocleavable devices for direct Mass detection from solid support.

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© 2005 The Pharmaceutical Society of Japan
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