チタンカーバイド／ポリエチレン導電性複合材料の粒子充填構造とPTC特性

抄録

Titanium carbide (TiC) / polyethylene (PE) composites have been prepared with various volume fractions of TiC by a melt blending method. Two types of TiC powder with their different particle diameters, 1.48 μm (TiC-A) and ca.100 μm (TiC-B), were utilized in the present study. The electric resistivities (ρ) of the samples decreased gradually with increasing TiC volume fraction (φ_A); in the case of smaller particle size, the value of ρ at room temperature jumped down in the relatively narrow range of φ_A = 0.39 - 0.42, reaching itself as low as 0.1 Ωcm. Temperature dependencies of ρ were also measured to examine the possible application of the composite to polymer PTC thermistors. The resistivity showed positive temperature dependence and changed abruptly in the tenth order of its magnitude during the melting transition of PE. The electric current-cutoff characteristics of the samples indicated excellent features in the over current response despite their low resistivity values, as compared with those of other PTC materials. In parallel, the mechanism of conductivity of the composite was discussed in terms of the percolation theory.