過酸化水素 : 低温プラズマ滅菌器内に生成するラジカル数の概算法に関する研究
1996 年 66 巻 1 号 p. 15-22
詳細
1996 年 66 巻 1 号 p. 15-22
An attempt to estimate the radicals numbers formed from hydrogenperoxide by plasma discharging technique in the apparatus (STERRAD 100, Johnson & Johnson Med. Co.) has been done using ascorbic acid (A. A) and diphenyl picryl hydrazyl (DPPH) as radical indicator. Then, the radical numbers were reduced from the adsorbance difference at λ max. on the spectra (on A. A : ultraviolet, on DPPH : visible ray) between before and after sterilizing using the Loschmidt's number, respectively. In result, it was found that the radical numbers were similar to the molecule numbers of H_2O_2 fed into the sterilizer before sterilizing. Moreover, it was guessed that ・O radical mainly reacted on A. A and ・OH radical mainly reacted on DPPH by the spectroscopic and gas chromatographic techniques.
