ISIJ International
Online ISSN : 1347-5460
Print ISSN : 0915-1559
ISSN-L : 0915-1559
Regular Article
The Effect of Zirconium Disilicide (ZrSi2) Additions on the Carbon Oxidation Behavior of Alumina/Graphite Refractory Materials
Arashk MemarpourVoicu BrabiePär G. Jönsson
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2010 Volume 50 Issue 11 Pages 1612-1621


Carbon oxidation is a main industrial problem for Alumina/Graphite Submerged Entry Nozzles (SEN) during pre-heating. Thus, the effect of ZrSi2 antioxidants and the coexistence of antioxidant additive and (4B2O3·BaO) glass powder on carbon oxidation were investigated at simulated non-isothermal heating conditions in a controlled atmosphere. Also, the effect of ZrSi2 antioxidants on carbon oxidation was investigated at isothermal temperatures at 1473 K and 1773 K. The specimens' weight loss and temperature were plotted versus time and compared to each others. The thickness of the oxide areas were measured and examined using XRD, FEG-SEM and EDS. The coexistence of 8 wt% ZrSi2 and 15 wt% (4B2O3·BaO) glass powder of the total alumina/graphite base refractory materials, presented the most effective resistance to carbon oxidation. The 121% volume expansion due to the Zircon formation during heating and filling up the open pores by (4B2O3·BaO) glaze during green body sintering led to an excellent carbon oxidation resistance.

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© 2010 by The Iron and Steel Institute of Japan
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