ISIJ International
Online ISSN : 1347-5460
Print ISSN : 0915-1559
ISSN-L : 0915-1559
Fundamentals of High Temperature Processes
Solubility of Sulfur in the Solid Oxide of the Calcium-Aluminate System
Sun-joong KimMasaaki KageyamaXu GaoShigeru UedaShin-ya Kitamura
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2019 Volume 59 Issue 10 Pages 1752-1755

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Abstract

The formation of CaS around CaO–Al2O3 causes pitting corrosion in ferritic stainless steel. To prevent the precipitation of CaS, the solubility of CaS in both the liquid and solid CaO–Al2O3 system has to be clarified. In this study, the sulfur content in the CaS-saturated solid CaO–Al2O3 system was measured. The results showed that, sulfur was soluble only in 12CaO·7Al2O3 at approximately 1.2 mass% while the sulfur content in the other solid compounds was very low. In addition, the sulfur content of 12CaO·7Al2O3 was independent of the heating temperature and was higher than that in the liquid oxide of the same composition. Therefore, 12CaO·7Al2O3 can dissolve sulfur in the solid state, preventing CaS formation.

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© 2019 by The Iron and Steel Institute of Japan
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