ISIJ International
Online ISSN : 1347-5460
Print ISSN : 0915-1559
ISSN-L : 0915-1559
Chemical and Physical Analysis
Accurate Online Measurement of Iron Concentration in Galvannealed Coating Layers by Shift of X-ray Diffraction Peak
Tomohiro Aoyama Hisato Noro
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2019 Volume 59 Issue 9 Pages 1599-1603

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Abstract

The authors have developed a new online measurement system for the Fe concentration in galvannealed (GA) coatings based on the proportionality between the peak angle of X-rays diffracted by the δ1 phase and the Fe concentration. The online system was realized by high-speed measurement of the peak angle of diffracted X-rays using a one-dimensional detector in conjunction with correction algorithm for the angular error caused by the displacement of the GA steel strip surface from the measurement position. The performance of the developed online system was demonstrated in a continuous galvanizing line with GA strips of Si-added and Si-free base steels. The developed system showed higher accuracy even with the Si-added base steel, with which enough accuracy could not be obtained with conventional online systems based on the diffraction intensity of the Γ phase. Since the δ1 phase is the major phase of GA coatings, the main advantage of the developed system is that its accuracy is less sensitive to the composition of the base steel.

Schematic diagram of measurement optics of online systems. (a) Developed online system in this paper, consisting of one-dimensional detector and laser displacement meter. (b) Conventional online system based on XRD intensity of Γ phase (J. Kawabe et al.: Kawasaki Steel Giho, 18(1992), 129.). Developed system achieves higher accuracy by high-speed measurement of the XRD peak angle of the δ1 phase and use of correction algorithm for angular error caused by vertical displacement of galvannealed steel strips. Fullsize Image
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© 2019 by The Iron and Steel Institute of Japan
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