Kinetics of the Non-isothermal Reduction of Cr₂O₃ with Aluminium

Abstract

The present paper presents the results of a thermoanalytical investigation on the kinetics of the aluminothermic reduction of Cr₂O₃ under non-isothermal conditions. Simultaneous differential thermal analysis (DTA) and thermogravimetry (TG) technique were used. It was determined the minimum molar ratio Cr₂O₃ : Al for the completion of the reaction and the value of the change of enthalpy associated to the reduction. X-ray diffraction was used in order to identify the products of reduction. Since the oxidation of aluminium and the reduction of Cr₂O₃ occur simultaneously, it was possible to study the kinetics by analysing the rate of generation of the peak area for the Cr₂O₃ reduction (DTA) and the mass gain due to the oxidation of some of the excess of aluminium (TG). The reduction was controlled by first order chemical reaction and the reduction was isokinetic within the experimental conditions of the present work.