Decomposition Kinetics of Glucose and Fructose in Subcritical Water Containing Sodium Chloride

Abstract

The kinetics of the decomposition and isomerization of glucose and fructose in pure water and water containing sodium chloride (1–20 % w/w) under subcritical conditions at 180–220 °C was investigated. The addition of sodium chloride in subcritical water accelerated the decrease of glucose, and the rate was expressed by the Weibull equation. Although the isomerization of glucose to fructose was observed in parallel with decomposition, the yield of fructose was lower at higher sodium chloride concentrations. Mannose was also formed from glucose with very low yield. It was seen that fructose decomposed much faster than glucose, in pure and salty subcritical water. The decomposition of fructose obeyed first-order kinetics in the initial stages of the reaction and could be expressed by the autocatalytic model in the later stages. The formation of glucose and mannose from fructose was not observed under any of the conditions investigated.