窯業協會誌
Online ISSN : 1884-2127
Print ISSN : 0009-0255
ポリシランとピッチの共熱分解縮合によるSiC-C繊維の前駆体の合成
長谷川 良雄岡村 清人
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95 巻 (1987) 1097 号 p. 109-113

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Precursors of carbon-containing SiC fibers (SiC-C fiber) were synthesized with high yield by the copyrolysis of poly (dimethylsilane) and 3.9-80wt% pitch. During copyrolysis the decomposition product of polysilane reacts with pitch molecule with no significant condensation among pitch molecules. SiC-C fibers were obtained by melt spinning of the precursors and heat-treatment up to 1400°C in vacuum. The tensile strength and Young's modulus of the SiC-C fiber decreased with increasing carbon content. The electric conductivity is two orders of magnitude larger than that of SiC fibers obtained from pure polycarbosilane.

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