Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌)
Online ISSN : 1882-1022
Print ISSN : 0914-5400
ISSN-L : 0914-5400
ペルオキソチタン酸溶液からのペルオキソ修飾されたアナターゼゾルの合成
一ノ瀬 弘道寺崎 信勝木 宏昭
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1996 年 104 巻 1212 号 p. 715-718

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A peroxo titanic acid (PTA) solution has been prepared by mixing titanic acid wet gel and hydrogen peroxide solution. The PTA solution was a neutral, transparent, stable liquid. The PTA crystallized to form an anatase phase after calcination at a temperature above 250°C. When the PTA solution was autoclaved at a temperature above 100°C for 6h, it changed to a sol containing anatase crystals less than 20nm in diameter. Aggregation occurred after autoclaving at a temperature above 120°C. When the PTA solution was heated to 100°C, it was translucent and stable in spite of containing ultrafine anatase crystals (9nm in diameter). It was deduced that the surfaces of anatase crystals are modified by the peroxo groups.

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