Journal of the Ceramic Society of Japan
Online ISSN : 1348-6535
Print ISSN : 1882-0743
ISSN-L : 1348-6535
Feature: Trends of Current Research on Organic-Inorganic Hybrid Materials: Papers
Novel hybrid luminescent materials derived from multicarboxy cage silsesquioxanes and terbium ion
Liguo LIShengyu FENGHongzhi LIU
著者情報
ジャーナル フリー
電子付録

2015 年 123 巻 1441 号 p. 719-724

詳細
抄録

Multicarboxy (8, 16) functionalized cage silsesquioxanes were synthesized through the photochemical thiol-ene reaction of octavinylsilsesquioxane with 3-mercaptopropionic acid and mercaptosuccinic acid, respectively. These two cage precursors acted as ligands to coordinate with terbium ion (Tb3+) to obtain two novel hybrid luminescent materials, which exhibited fine luminescent properties and good thermal stabilities. Their morphologies were investigated by XRD, SAXS, SEM, TEM and DLS. And the results showed that self-assembly particle size of the hybrid complex with octacarboxyl cage was larger size than that of cage with 16 carboxyl groups.

著者関連情報
© 2015 The Ceramic Society of Japan
前の記事 次の記事
feedback
Top