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Journal of Chemical Software
Vol. 8 (2002) No. 2 P 41-46

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http://doi.org/10.2477/jchemsoft.8.41

Original Papers

A program written in JAVA language was developed for the virtual electrochemical measurement of a modified electrode with a finite diffusion thickness, e.g., an electrode coated with polymer film in which functional molecules were dispersed. This program, called ES-2, can simulate cyclic voltammetry and potential-step chronoamperospectrometry by considering the rate of charge injection from the electrode to the functional molecule and the diffusion of charge. The results are shown by a voltammogram (I-V curve), and concentration distribution in the layer at a series of voltages at cyclic voltammogram mode, I-t curve, and time dependence of concentration distribution in the layer at potential step mode and a text of current values, the fraction of the oxidized molecules (RCT) and parameters used for the simulation in both modes. A dynamic textbook of electrochemistry can be constructed by this program combined with HTML text.

Copyright © 2002 by the Chemical Software Society of Japan

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