日本結晶学会誌
Online ISSN : 1884-5576
Print ISSN : 0369-4585
ISSN-L : 0369-4585
総合報告
π共役金属ジチオレン錯体の新次元展開
草本 哲郎神戸 徹也西原 寛
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2013 年 55 巻 6 号 p. 323-330

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The development of functional metalladithiolene complexes was described. Photo-, magneto-, and electro-functional moieties were hybridized with a metalladithiolene backbone to produce novel electronic properties, such as photo-controlled three-state switching, and a SOMO-HOMO converted electronic structure. Long range electronic communication and three-dimensional clusterization were achieved on triangular trinuclear metalladithiolene complexes. The atomiclayer nickel dithiolene nanosheet was successfully prepared, in which nickel bis(dithiolene)moieties were connected through benzene skeletons to form a fully π-conjugated hexagonal structure in two dimensions. The electric properties of the stacked nanosheets were modulated by chemical redox reaction.

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