2013 年 55 巻 6 号 p. 345-349
Long-period structures of homologous phases Ga2O3(ZnO)m are closely related to the wurtzite structure of ZnO, and structural evolution is discussed based on the results from structure analyses. A unified structure model for Ga2O3(ZnO)m is established in(3+1)dimensional superspace. Zig-zag functions with large amplitudes are used as modulation functions in the model, which is a common feature in structures constructed by the so-called unit-cell twining. Advantages of the superspace description for homologous phases are explained in relation to the process of identification of materials.