大環状シクロファン包接体の構造
1986 年 28 巻 4 号 p. 261-272
詳細
1986 年 28 巻 4 号 p. 261-272
The crystallographic study of macrocyclic cyclophane inclusion compounds is reviewed. Cyclophanes such as [2.2.2], [6.6.6], [3.3.3.3] and [6.1.6.1] paracyclophanes and calixarenes with intramolecular hydrophobic cavities surrounded by benzene walls incorporate neutral guest molecules to give molecular inclusion compounds (cavitate) in solutions and in the solid state. Tri-o-thymotide forms chiral single crystals of cage type or channel type clathrate which have enantiomeric excess of guest molecules. [J. Cryst. Soc. Jpn. 28, 261 (1986) ] .
