コバルト (III) 錯体のニトローニトリト結合異性化反応
1995 年 37 巻 1 号 p. 62-68
詳細
1995 年 37 巻 1 号 p. 62-68
Nitrite ion is a well-known ligand which shows linkage isomerism. The photo-isomerization in the solid state is governed by at least two factors: (a) electronic effect by coexisting ligands, and (b) reaction cavity of the nitro group. Recent X-ray study has revealed that the nitro-nitrito photo isomerization in a crystal is severely governed by intermolecular steric restrictions.
