日本結晶学会誌
Online ISSN : 1884-5576
Print ISSN : 0369-4585
ISSN-L : 0369-4585
回折法とXAFS法を併用した不規則構造解析―α-Agl型構造の超イオン導電機構―
吉朝 朗
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2006 年 48 巻 1 号 p. 30-35

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The Debye-Waller factors determined by diffraction and XAFS experiments provide important information about the thermal vibration and disordered structure. The statistical distribution of Ag in α-AgI and supersonic conduction mechanism have been discussed based on the effective one-particle potential, probability density function and effective pair potential. The disordered nature of α-AgI is due to the thermal motion and the probability of finding mobile Ag ions at saddle point is a few percent in α-AgI.

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