日本結晶学会誌
Online ISSN : 1884-5576
Print ISSN : 0369-4585
ISSN-L : 0369-4585
金属内包フラーレンの構造
赤阪 健永瀬 茂
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ジャーナル フリー

2006 年 48 巻 3 号 p. 230-235

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The structures of many typical endohedral metallofullerenes have been reported by the powder X-ray analysis. For example, the report of the trimetallofullerene Sc3C82has shown that the endohedral structure is Sc3@C82, this being widely accepted. However, the recent13C NMR spectroscopy and X-ray single crystal analysis have revealed that the structure of Sc3C82is not Sc3@C82but Sc3C2@C80. This may suggest that the endohedral structures reported from the powder X-ray study are not always reliable even in a qualitative sense.

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