日本結晶学会誌
Online ISSN : 1884-5576
Print ISSN : 0369-4585
ISSN-L : 0369-4585
単元素バルクメタリックガラスは, 存在するか?
~高温高圧下におけるZr, Tiの非晶質化の検証~
服部 高典, 齋藤 寛之, 青木 勝敏, 金子 洋, 岡島 由佳, 内海 渉
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2007 年 49 巻 3 号 p. 179-185

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The high-pressure formation of the bulk metallic glass of elemental Zr and Ti, which has been recently reported, is verified by a newly developed angle dispersive X-ray diffraction (ADX) system using a large volume multi-anvil apparatus equipped with X-ray transparent anvils. The ADX data revealed that Zr and Ti remain as a crystalline form at high-pressure and temperature condition where the amorphization has been reported. The misinterpretation in the previous papers is attributed to the anomalous rapid grain growth that is related to the characteristic lattice dynamic and the resulting anomalously fast self diffusion in the high-temperature phases of Zr and Ti.
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