Old Nakagawa River is located in eastern part of Tokyo, 6.68km long, and runs along Arakawa River. The river is semi-closed to Arakawa River. River water and sediment samples were collected from 18 and 5 sites from Old Nakagawa River and Arakawa River, respectively. River water samples were analyzed for Na+ and K+ by AAS (atomic absorption spectroscopy), anions (Cl-, SO42-, Br-, NO3-, PO43-) by ion chromatography, and trace metals (Cd, Cr, Cu, Mo, Ni, Pb, Zn) by ICP-MS (inductively coupled plasma mass spectrometry). River sediments samples were analyzed for mineral identification by XRD (X-ray diffraction), and for trace metals (Cd, Cr, Cu, Mo, Ni, Pb, Zn) by ICP-MS. Cr6+ concentrations in river water and sediment samples were analyzed by fixations of Cr6+ by CaHPO4. Five step extraction method by Hall et al. (1996) was used to clarify the proportion of trace metals in each step (extracted solution) for the river sediment samples. I-geo (geoaccumulation index) and EF (enrichment factor) for the trace metals calculated from analytical data on river sediments samples are very high, indicating that the river sediments are highly polluted. Cr6+ in the river water and sediments samples was not detected, although ΣCr in sediments sample is very high, indicating Cr is present as 3+ in the sediments and water, and Cr in sediments is not mobile. Trace metal elements are classified into three groups. They are (A) Cd and Zn which exist mainly as AEC (adsorption- ion exchangeable) and acid soluble (carbonate) fraction, (B) Cu and Pb which exist mainly as amorphous and Fe oxyhydroxide occluded fraction, and (C) Cr and Ni which exist as various fractions.