2011 年 90 巻 5 号 p. 461-465
We have investigated dependence of device characteristics of bulk-heterojunction organic thin-film solar cells on concentration of glycerol addition to poly (3,4-ethylenedioxy thiophene) : poly (4-styrene sulfonate) (PEDOT:PSS) solutions for fabricating buffer layers. The device structure is ITO/buffer/regioregular poly (3-hexylthiophene) (P3HT):[6,6]-phenyl C61-butyric acid methylester (PCBM)/Al where glycerol concentration is up to 13.0 wt%. Glycerol addition is effective for improving power conversion efficiency (PCE) from 1.25 to 1.41% because of increase in short-circuit current density (Jsc) without decreasing open-circuit voltage (Voc).