日本エネルギー学会誌
Online ISSN : 1882-6121
Print ISSN : 0916-8753
ISSN-L : 0916-8753
150t/d規模石炭液化パイロットフ.ラントによる開発研究 (IV)
循環溶剤および溶剤水素化反応に関する検討
高津 淑人小山 和英小根山 稔荒牧 寿弘石橋 宏仁小野 崎正樹林 隆小林 正俊
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1999 年 78 巻 2 号 p. 120-128

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Activity of solvent hydrogenation catalyst was investigated from charactarization of recycle solvent in the 150t/d bituminous coal liquefaction pilot plant. The following conclusions are obtained.
(1) In the pilot plant, solvent hydrogenation catalyst exhibits high activity for hydrogenation of aromatic compounds. This activity gives hydrogendonability to recycle solvent.
(2) Recycle solvent mainly consists of tworings aromatic compounds, and increase of more condensed aromatic compounds (over three rings) in the solvent causes decrease of the reaction rate constant.
(3) The reaction rate at the pilot plant is higher than that at PSU and bench scale unit. This results from difference of compositions of the solvents and contacting effectiveness among these facilities. Therefore, it's so important for conceptual design work to evaluate these influences.

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