2006 年 9 巻 6 号 p. 485-489
The relationship between the chemical structure and dielectric loss tangent (tan δ) of various organophosphate flame retardants was studied. It was presumed that the low tan δ of organophosphate results from its structure, which retards the rotation of substituents inside the molecules. Resorcinol bis (dixylenylphosphate) (D) and 10- (2, 5-dihydroxyphenyl) -10H-9-oxa-10-phosphaphenan-threne=10-oxido (F) have chemical structures with a bulky xylene or a rigid cyclic bond, and these organophosphate compounds have a low tan S. Organophosphate (D) and (F) also work as effective flame retardants without influencing the tanδof a resin. The tan δ of cured 1, 2-bis (vinylphenyl) ethane/poly (phenylene oxide) (BVPE/PPO) resin containing 30 phr of organophosphate (D) or (F) was 0.0019-0.0022, while the average burning time was 0-1 sec.