石炭科学会議発表論文集
Online ISSN : 2423-8309
Print ISSN : 2423-8295
ISSN-L : 2423-8295
第53回石炭科学会議
セッションID: No.2-6
会議情報

ガス化・燃焼 (6)、その他 (1)
No.2-6 石炭火力ボイラ伝熱面の噴霧塗装による硫化腐食対策
河瀬 誠森永 雅彦
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会議録・要旨集 フリー

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In thermal power generation equipment, wall thinning on boiler tubes due to sulfide corrosion has been a problem. The methods for resolving or preventing the problem are coating of a nickel-chromium film by plasma spraying, weld cladding, and replacement of water wall tubing. These methods are expensive and time consuming. Therefore, an economical and straightforward coating technique was developed for preventing sulfide corrosion on boiler tubes. The developed coating (CRIEPI coating) has a four-layered structure comprising, in order from the boiler tube substrate, thin films of (1) a SiO2 layer, (2) a TiO2 layer, (3) an Al2O3-based layer, and (4) a TiO2 layer. CRIEPI coating reduced corrosion to 25% or less compared with an uncoated part. It was found that CRIEPI coating on boiler tubes is exceptionally durable and continues to be effective for more than 2 years in actual power plants.

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