有機超伝導体の物質探索と結晶成長 : Part1 機能性有機分子の分子設計と結晶成長

抄録

An overview of the crystal growth of organic molecular complexes which include organic metals snd superconductors is presented. Organic molecular complexes are classified into several groups (mainy proton-transfer and charge-transfer type) according to the intermolecular interactions of component materials. All organic conductors so far known are of charge-transfer type. They are prepared by the redox reactions such as i) a direct reaction of donor and acceptor in gas, liquid or solid phases, ii) metathesis, and iii) electrocrystallization. Several examples of the crystal growth of conducting organic compounds prepared by these redox methods are described.