The goal of this study is to produce a high Tc superconductive film with a wide area using the productive plasma spraying technique. As the first step of this study, the possibility of recovering the superconductive crystal and its related characteristics which has been destroyed during the plasma spraying operation is discussed. The well known superconductive powder of Bi2Sr2CaCu2Ox was used as the raw material. More specifically, the powder was first plasma sprayed onto a stainless steel substrate and followed by a CO2 laser beam irradiation together with the oxygen gas flow intended to remodify the crystal structure of the film. The resultant film was first checked with respect to its crystalline condition through the SEM observation and X-ray diffraction analysis, and then followed by the measurement of its superconductive critical temperatures of Tc (on) and Tc (end). The results showed that the laser post-treatment can recover the superconductive crystal on the plasma sprayed film and can provide a critical temperature of 62K (Tc (end)) on the film.