粉体および粉末冶金
Online ISSN : 1880-9014
Print ISSN : 0532-8799
種々の雰囲気での(Ca, Sr)CuO2の合成と元素置換
小川 稔武田 保雄今西 誠之山本 治
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40 巻 (1993) 11 号 p. 1037-1040

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The solid solution region of infinite-layered copper oxide Ca1-xSrxCuO2 was studied under various oxygen partial pressure.The stability region expanded with decreasing oxygen pressure. The trials for electron or hole doping were tried, the intercalation of Li ion by the discharge in Li-battery was possible forming (Ca0.85Sr0.15)0.9LixCuO2(x ?? 0.2). Both a and c axes increased with increasing x, indicating the reduction of oxidation state of Cu, but it did not bring about superconductivity.

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