粉体および粉末冶金
Online ISSN : 1880-9014
Print ISSN : 0532-8799
SnxCo4Sb12スクッテルダイトの熱電特性に及ぼすスズ原子挿入の効果
滝沢 博胤伊藤 雅之上田 恭太遠藤 忠
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47 巻 (2000) 11 号 p. 1170-1174

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Thermoelectric properties of tin-filled skutterudites, SnxCo4Sb12, are evaluated. The tin-filled compounds were synthesized under high pressure and temperature condition from powder mixture of CoSb3 and elemental tin. The tin-filled compounds exhibit n-type semiconducting behavior indicating that the incorporation of tin atoms causes the formation of a donor level. A remarkable reduction in the thermal conductivity was achieved by tin insertion. Thermal conductivity of the tin-filled sample is two orders of magnitude lower than that of the unfilled CoSb3. Effect of void filling on the thermoelectric properties of SnxCo4Sb12 is compared to that of other filled skutterudites. It is concluded that tin atom is a better "rattler" in the CoSb3 host lattice.

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