1960 Volume 38 Issue 4 Pages 195-199
In order to investigate the influence of the impurities dissolved in water droplets upon their freezing, the following experiment was carried out : aqueous dilute solutions of electrolyte were dispersed, with the aid of a nebulizer, to fogs of droplet size of 8μ diameter in average, and their freezing temperatures were observed in a thermostatlike cold chamber maintained at temperatures from -5°to -40°C. As for the electrolytes used, NaCI, NaBr, NaI, KCI, KBr, and KI were selected as the 1 to 1-valent type salt, BaCl2, BaBr2 and BaI2 as the 2 to 1-valent type salt, and further, A1C13 and A1Br3 as the 3 to 1-valent type salt.
The results were such that (1) the freezing temperature varies with the concentration of electrolyte, and the highest temperatures are found at the concentrations of approximately 10-4, 10-6, and 10-8N for 1 to 1-, 2 to 1- and 3 to 1-valent type salts, respectively; and (2) with the electrolytes tested, the freezing temperature falls into the series I- (highest) >Br->Cl- (lowest) so far as the same metal ion is concerned.