油化学
Online ISSN : 1884-2003
ISSN-L : 0513-398X
リモネンとアクリル酸メチルの反応
須賀 恭一菊地 英夫渡辺 昭次藤田 力滝口 良平
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1978 年 27 巻 11 号 p. 802-804

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Thermal and aluminium chloride catalytic addition for the reaction of d-Limonene with methyl acrylate gave a mixture of methyl 5- (4-methyl-3-cyclohexen-1-yl) -5-hexenoate (2) and methyl 5- (4-methyl-3-cyclohexen-1-yliden) hexanoate (3) in the yield of 23%. From the reaction of methylmagnesium iodide and the compound (2), 2-methyl-6- (4-methyl-3-cyclohexen 1-yl) -6-hepten 2-ol (4) was obtained. By the dehydration of the compound (4) with potassium bisulfate, a mixture of β-bisabolene and its isomers was obtained.

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