Journal of Pesticide Science
Online ISSN : 1349-0923
Print ISSN : 1348-589X
ISSN-L : 0385-1559
Metabolism of DTP, the Herbicidal Entity of Pyrazolate, in Rice Plants
Mitsuru ANDOKatashi YAMAOKAYoshio SHIGEMATSUMasayuki NAKAGAWAMitsuo ISHIDA
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1988 Volume 13 Issue 4 Pages 579-585

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Abstract
Absorption, translocation and metabolism of DTP [4-(2, 4-dichlorobenzoyl)-1, 3-dimethyl-5-hydroxypyrazole], the hydrolysate and herbicidal entity of pyrazolate, in rice plants was studied by using 14C-preparations labeled either at the pyrazole ring or at the benzene ring under a water-culture condition. DTP was readily absorbed into the roots, rapidly metabolized and part of the radioactivity was translocated into the foliages. The metabolism of DTP involved hydroxylation of the 3-methyl group and subsequent oxidation to carboxyl group, demethylation of the 1-methyl group, cleavage of 2, 4-dichlorobenzoyl linkage, and conjugation.
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© Pesticide Science Society of Japan
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