Abstract
To reduce CO2 emission and environmental impact, it is needed to develop the clean and higher efficiency power generation system. So, the CO2 recovering semi closed gas turbine with CH4-O2 firing has been noted with its high efficiency and low emission capability. Such a high efficiency is a result of a high turbine inlet temperature. Though, high temperature causes the increase of emission level such as CO and H2 because of an incomplete reaction. Although, incomplete reaction can be suppressed in an oxidation surroundings actualized by excess oxygen feeding, it causes a decrease of system efficiency. So, chemical kinetic calculations are carried out to clarify the trade-off relationship between these parameters. The characteristics of pollutant formation and its oxidation processes are analyzed. An optimal equivalent ratio for the total system efficiency and emission is also estimated.