材料
Online ISSN : 1880-7488
Print ISSN : 0514-5163
ISSN-L : 0514-5163
高張力鋼の過防食下における腐食疲労き裂進展
駒井 謙治郎箕島 弘二山本 和利
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1984 年 33 巻 374 号 p. 1407-1413

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The influence of cathodic overprotection at E=-1.2V vs. SCE (Saturated Calomel Electrode) on the corrosion fatigue crack growth behavior of a high-tensil steel HT80 has been invesitgated at R=0.1-0.8 and f=0.1-0.01Hz in 3.5%NaCl solution. The major acceleration factors dominating corrosion fatigue crack growth behavior under cathodic overprotection have been discussed. At the free corrosion potential (E=Ec), an acidified solution within cracks (pH=2) made the crack wall dissolve and the crack blunting, which causes a decrease in Kop from that in dry air. At E=-1.2V vs. SCE the pH value within cracks was 10, causing an increase in Kop due to the caustic corrosion products (caustic corrosion-products induced wedge-effect). The effect of load ratio on da/dN at E=Ec was negligible in terms of ΔKeff. At E=-1.2V vs. SCE da/dN at R=0.8 accelerated from those at R<0.8 at high ΔKeff, which was brought about by static SCC being dominating crack growth behavior. On the other hand, da/dN became greater as the frequency decreased both at E=Ec and E=-1.2V vs. SCE. The major acceleration factor was hydrogen embrittlement at E=Ec, whilst they were hydrogen embrittlement and stress-assisted caustic dissolution at low ΔKeff, and hydrogen embrittlement at high ΔKeff at E=-1.2V vs. SCE.

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