表面科学
Online ISSN : 1881-4743
Print ISSN : 0388-5321
第36回表面科学学術講演会特集号 [II]
シリコン基板に担持された単原子層単一サイズ白金クラスターの特異的触媒活性とクラスター・担体間相互作用
安松 久登福井 信志
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38 巻 (2017) 8 号 p. 406-412

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Preparation, catalytic activity and thermal stability of monatomic-layered uni-sized platinum cluster disks directly bound to a single-crystal Si surface are reviewed. The cluster disks were prepared by impact of uni-sized cluster ions onto the surface: cluster impact. Their catalytic activity in the CO oxidation was unveiled through surface-chemistry measurements; the low-temperature catalytic activity and reaction sites involved in the CO oxidation were studied with temperature-programed desorption (TPD) measurements, and anti-poisoning ability against CO around room temperature was elucidated by measuring the turnover rate in gas-flow reactions under steady-state conditions. The thermal stability was evaluated by means of scanning-tunneling microscope (STM) with repetition of the sample heating. These specific properties of the cluster disks were explained according to electron accumulation at the sub-nano interface between the cluster disk and the substrate surface through strong chemical interaction between them.

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