表面科学
Online ISSN : 1881-4743
Print ISSN : 0388-5321
ISSN-L : 0388-5321
変調構造を有するビスマス系複合酸化物の表面構造の高分解能電顕観察
柳澤 佳寿美松井 良夫正田 薫室町 英治堀内 繁雄
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1992 年 13 巻 5 号 p. 275-278

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Terraced surfaces of Bi-Co complex oxide, (Bi, Pb)2Sr2CoOy, are examined by means of high-resolution transmission electron microscope (HRTEM) profile imaging method. The outermost surface of each step is a single (BiO) layer, which preserves wavy fluctuations of atom-plane almost in the same manner as those in the bulk-modulation. Some of (BiO)-layers near the edge of the crystal are not double but single (BiO) layers. In addition, an extremely small crystal of Bi2 (Sr, Ca)3Cu2Oy with unit-cell-size width is found to have the modulated structure almost identical with the bulk-modulation.

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