表面科学
Online ISSN : 1881-4743
Print ISSN : 0388-5321
ISSN-L : 0388-5321
高温におけるZr-O/W系の表面組成に関する研究
李 壽燦田村 仁志井上 雅彦志水 隆一
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1994 年 15 巻 4 号 p. 268-272

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Surface chemical analysis of Zr-O/W system was performed at two different sample temperatures, room temperature and ∼1600 K, by using Auger electron spectroscopy (AES) and ion scattering spectroscopy (ISS). Depositing Zr onto a polycrystalline W-substrate the surface was exposed to oxygen. AES and ISS measurements have revealed that the oxygen adsorbed on the Zr/W surface at room temperature diffuses into Zr/W at ∼1600 K, keeping a major part of Zr remained on the outermost atomic layer. This result strongly supports the model proposed by Danielson and Swanson for Zr-O/W (100) system that the oxygen adsorbed on the Zr/W (100) surface at room temperature diffuses into the Zr/W (100) as a composite Zr-O at high temperature and this results in considerable decrease of work function, leading the Zr-0/W (100) system to an electron source of high brightness.

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