Application of New Solid-state NMR Techniques to Microporous Materials

Shigenobu HAYASHI

doi:10.1380/jsssj.18.705

Shigenobu HAYASHI

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JOURNAL FREE ACCESS

1997 Volume 18 Issue 11 Pages 705-710

DOI https://doi.org/10.1380/jsssj.18.705

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Published: November 10, 1997 Received: January 06, 1997 Available on J-STAGE: August 07, 2009 Accepted: January 06, 1997 Advance online publication: - Revised: -
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Date of correction: August 07, 2009 Reason for correction: - Correction: CITATION Details: Wrong : 1) G. Engelhardt and D. Michel: “High-Resolution Solid-State NMR of Silicates and Zeolites” (John Wiley & Sons, Chichester, 1987).
2) C.A. Fyfe, Y. Feng, H. Grondey, G.T. Kokotailo and H. Gies: Chem. Rev. 91,1525 (1991).
3) C.A. Fyfe, K.T. Mueller, H. Grondey and K.C. Wong-Moon: J. Phys. Chem. 97, 13484 (1993).
4) C.A. Fyfe, K.C. Wong-Moon and Y. Huang: Zeolites 16, 50 (1996).
5) C.A. Fyfe, K.C. Wong-Moon, Y. Huang, H. Grondey and K.T. Mueller: J. Phys. Chem. 99, 8707 (1995).
6) C.A. Fyfe, K.C. Wong-Moon, Y. Huang and H. Grondey: Micropor. Mater. 5, 29 (1995).
7) M. Hunger: Solid State Nucl. Magn. Reson. 6, 1(1996).
8) T. Baba, Y. Inoue and Y. Ono: J. Catal.159, 230 (1996).
9) M. Hunger, S. Ernst, S. Steuernagel and J. Weitkamp: Micropor. Mater. 6, 349 (1996).
10) D. Freude: Chem. Phys. Lett. 235, 69 (1995).
11) C.P. Grey and A.J. Vega: J. Am. Chem. Soc. 117, 8232 (1995).
12) H. Sachsenröder, E. Brunner, M. Koch, H. Pfeifer and B. Staudte: Micropor. Mater. 6, 341 (1996).
13) C.S. H. Chen and S.E. Schramm: Micropor. Mater. 7,125 (1996).
14) C.P. Grey and B.S.A. Kumar: J. Am. Chem. Soc. 117, 9071 (1995).
15) H.-M. Kao and C.P. Grey: J. Phys. Chem. 100, 5105 (1996).
16) H.-M. Kao and C.P. Grey: Chem. Phys. Lett. 259, 459 (1996).
17) For example, P.J. Barrie, M. E. Smith and J. Klinowski: Chem. Phys. Lett.180, 6(1991).
18) R. Jelinek, S. Özkar, HO. Pastore, A. Malek and G.A. Ozin: J. Am. Chem. Soc. 115, 563 (1993).
19) H.A.M. Verhulst, W.J.J. Welters, G. Vorbeck, L.J.M. van de Ven, V.H.J. de Beer, R.A. van Santen and J.W. de Haan: J. Phys. Chem. 98, 7056 (1994).
20) L. Frydman and J.S. Harwood: J. Am. Chem. Soc. 117, 5367 (1995).
21) C. Fernandez and J.P. Amoureux: Chem. Phys. Lett. 242, 449 (1995).
22) C. Fernandez, J.P. Amoureux, L. Delmotte and H. Kessler: Micropor. Mater. 6,125 (1996).
23) C. Fernandez, J.P. Amoureux, J.M. Chezeau, L. Delmotte and H. Kessler: Micropor. Mater. 6, 331(1996).

Right : 1) G. Engelhardt and D. Michel: “High-Resolution Solid-State NMR of Silicates and Zeolites” (John Wiley & Sons, Chichester, 1987).
2) C.A. Fyfe, Y. Feng, H. Grondey, G.T. Kokotailo and H. Gies: Chem. Rev. 91,1525 (1991).
3) C.A. Fyfe, K.T. Mueller, H. Grondey and K.C. Wong-Moon: J. Phys. Chem. 97, 13484 (1993).
4) C.A. Fyfe, K.C. Wong-Moon and Y. Huang: Zeolites 16, 50 (1996).
5) C.A. Fyfe, K.C. Wong-Moon, Y. Huang, H. Grondey and K.T. Mueller: J. Phys. Chem. 99, 8707 (1995).
6) C.A. Fyfe, K.C. Wong-Moon, Y. Huang and H. Grondey: Micropor. Mater. 5, 29 (1995).
7) M. Hunger: Solid State Nucl. Magn. Reson. 6, 1(1996).
8) T. Baba, Y. Inoue and Y. Ono: J. Catal.159, 230 (1996).
9) M. Hunger, S. Ernst, S. Steuernagel and J. Weitkamp: Micropor. Mater. 6, 349 (1996).
10) D. Freude: Chem. Phys. Lett. 235, 69 (1995).
11) C.P. Grey and A.J. Vega: J. Am. Chem. Soc. 117, 8232 (1995).
12) H. Sachsenröder, E. Brunner, M. Koch, H. Pfeifer and B. Staudte: Micropor. Mater. 6, 341 (1996).
13) C.S. H. Chen and S.E. Schramm: Micropor. Mater. 7,125 (1996).
14) C.P. Grey and B.S.A. Kumar: J. Am. Chem. Soc. 117, 9071 (1995).
15) H.-M. Kao and C.P. Grey: J. Phys. Chem. 100, 5105 (1996).
16) H.-M. Kao and C.P. Grey: Chem. Phys. Lett. 259, 459 (1996).
17) For example, P.J. Barrie, M. E. Smith and J. Klinowski: Chem. Phys. Lett.180, 6(1991).
18) R. Jelinek, S. Özkar, HO. Pastore, A. Malek and G.A. Ozin: J. Am. Chem. Soc. 115, 563 (1993).
19) H.A.M. Verhulst, W.J.J. Welters, G. Vorbeck, L.J.M. van de Ven, V.H.J. de Beer, R.A. van Santen and J.W. de Haan: J. Phys. Chem. 98, 7056 (1994).
20) L. Frydman and J.S. Harwood: J. Am. Chem. Soc. 117, 5367 (1995).
21) C. Fernandez and J.P. Amoureux: Chem. Phys. Lett. 242, 449 (1995).
22) C. Fernandez, J.P. Amoureux, L. Delmotte and H. Kessler: Micropor. Mater. 6,125 (1996).
23) C. Fernandez, J.P. Amoureux, J.M. Chezeau, L. Delmotte and H. Kessler: Micropor. Mater. 6, 331(1996).

Abstract

Application of recently developed solid-state NMR techniques to microporous materials such as zeolites and AlPO₄ has been introduced. The connectivity of X-Y spin pairs can be examined by dipolar dephasing difference (or TRAP-DOR), cross polarization (CP), REDOR and TEDOR experiments. Those techniques are applied to study the connectivity of Al-O-P and Al-O-Si in the framework structure. They are also applied to study the surface property in terms of the interaction between the surface and adsorbed molecules containing N and P. High resolution solid-state NMR spectra of half-integer quadrupole nuclei such as ²⁷Al and ²³Na can be obtained by two-dimensional multiple-quantum spectra under MAS, which has been applied to study Al sites in AlPO₄.

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