Kinematic Study of Isotope Effect of Erosion Reaction at C:H Film Surfaces
1997 年 18 巻 2 号 p. 93-96
詳細
1997 年 18 巻 2 号 p. 93-96
We have calculated the rates of the erosion reaction by the steady-state approximation to confirm its isotope effect at C:H film surfaces observed experimentally. The isotope effect is due to the difference between activation energies of C-H and C-D bond breakings along the reaction coordinate. Calculated results are in good agreement with experimental ones.
