XPS Study on Dissociative Adsorption of NO on Polycrystalline Rh

Takeru SAITO; Fumitaka ESAKA; Keiichi FURUYA; Hiromichi SHIMADA; Motoyasu IMAMURA; Nobuyuki MATSUBAYASHI; Toshio SATO; Akio NISHUIMA; Tadashi KIKUCHI

doi:10.1380/jsssj.19.179

XPSによる多結晶Rh表面におけるNOの解離吸着挙動の検討

斉藤健, 江坂文孝, 古谷圭一, 島田広道, 今村元泰, 松林信行, 佐藤利夫, 西嶋昭生, 菊池正

著者情報

ジャーナルフリー

1998 年 19 巻 3 号 p. 179-185

DOI https://doi.org/10.1380/jsssj.19.179

詳細

発行日: 1998/03/10 受付日: 1997/08/14 J-STAGE公開日: 2009/08/07 受理日: 1997/09/05 早期公開日: - 改訂日: -
訂正情報
訂正日: 2009/08/07 訂正理由: - 訂正箇所: 引用文献情報訂正内容: Wrong : 2) M. Iwamoto and H. Yahiro: Catal. Today 22, 5 (1994).
3) M. Shelef and G.W. Graham: Catal. Rev. Sci. Eng. 36 433 (1994).
4) M. Bowker, Q. Guo and R.W. Joyner: Surf. Sci. 257, 33 (1991).
5) R.J. Baird, R.C. Ku and P. Wynblatt: Surf. Sci. 346, 97 (1980).
6) A. Baraldi, V.R. Dhanak, M. Kiskinova and R. Rosei: Appl. Surf. Sci. 78, 445 (1994).
7) A. Baraldi, M. Barnaba, B. Brena, D. Cocco, G. Comelli, S. Lizzit, G. Paolucci and R. Rosei: J. Electron Spectrosc. Relat. Phenom. 76, 145 (1995).
8) A. Morganate, D. Cveko, A. Santoni, K.C. Prince, V.R. Dhanak, G. Comelli and M. Kiskinova: Surf. Sci. 285, 227 (1993).
9) T.W. Root, L.D. Schmidt and G.B. Fisher: Surf. Sci. 134, 30 (1983).
10) S. Lizzit, G. Comelli, Rh. Hofmann, G. Paolucci, M. Kiskinova and R. Rosei: Surf. Sci. 276,144 (1992).
11) H.A.C.M. Hendrickx and B.E. Nieuwenhuys: Surf. Sci. 175,185 (1986).
12) C. Sellmer, V. Schmatloch and N. Kruse: Catal. Lett. 35, 165 (1995).
13) P. Ho and J. M. White: Surf. Sci. 137, 103 (1984).
14) G. Comelli, S. Lizzit, Rh. Hofmann, G. Paolucci, M. Kiskinova and R. Rosei: Surf. Sci. 277, 31(1992).
15) G. Comelli, Rh. Hofmann, G. Paolucci, M. Kiskinova and R. Rosei: Surf. Sci. 276,144 (1992).
16) S. Sugai, K. Takeuchi, T. Ban, H. Miki and K. Kawasaki: Surf. Sci. 282, 67 (1991).
17) R. I. Masel: Catal. Rev. Sci. Eng. 28, 335 (1986).
18) A.T.S. Wee, J. Lin, A.C.H. Huan, F.C. Loh and K.L. Tan: Surf. Sci. 304,145 (1994).
19) S.K. So, R. Franchy and W. Ho: J. Chem. Phys. 91, 5701 (1989).
20) J. Randnik, F. Gimans, B. Pennemann, K. Oster and K. Wandret: Surf. Sci. 287/288, 330 (1993).
21) R.D. Ramsier, Q. Gao, H. Neergaard Waitenburg, K.-W. Lee, OW. Nooij, L. Lefferts and J.T. Yates, Jr.: Surf. Sci. 320, 209 (1994).
22) J.A. Rodriguez and J. Hrbek: J. Vac. Sci. Technol. A 12, 2140 (1994).
23) J. Stöhr and R. Jaeger: Phys. Rev. B 26, 4111(1982).

Right : 2) M. Iwamoto and H. Yahiro: Catal. Today 22, 5 (1994).
3) M. Shelef and G.W. Graham: Catal. Rev. Sci. Eng. 36 433 (1994).
4) M. Bowker, Q. Guo and R.W. Joyner: Surf. Sci. 257, 33 (1991).
5) R.J. Baird, R.C. Ku and P. Wynblatt: Surf. Sci. 346, 97 (1980).
6) A. Baraldi, V.R. Dhanak, M. Kiskinova and R. Rosei: Appl. Surf. Sci. 78, 445 (1994).
7) A. Baraldi, M. Barnaba, B. Brena, D. Cocco, G. Comelli, S. Lizzit, G. Paolucci and R. Rosei: J. Electron Spectrosc. Relat. Phenom. 76, 145 (1995).
8) A. Morganate, D. Cveko, A. Santoni, K.C. Prince, V.R. Dhanak, G. Comelli and M. Kiskinova: Surf. Sci. 285, 227 (1993).
9) T.W. Root, L.D. Schmidt and G.B. Fisher: Surf. Sci. 134, 30 (1983).
10) S. Lizzit, G. Comelli, Rh. Hofmann, G. Paolucci, M. Kiskinova and R. Rosei: Surf. Sci. 276,144 (1992).
11) H.A.C.M. Hendrickx and B.E. Nieuwenhuys: Surf. Sci. 175,185 (1986).
12) C. Sellmer, V. Schmatloch and N. Kruse: Catal. Lett. 35, 165 (1995).
13) P. Ho and J. M. White: Surf. Sci. 137, 103 (1984).
14) G. Comelli, S. Lizzit, Rh. Hofmann, G. Paolucci, M. Kiskinova and R. Rosei: Surf. Sci. 277, 31(1992).
15) G. Comelli, Rh. Hofmann, G. Paolucci, M. Kiskinova and R. Rosei: Surf. Sci. 276,144 (1992).
16) S. Sugai, K. Takeuchi, T. Ban, H. Miki and K. Kawasaki: Surf. Sci. 282, 67 (1991).
17) R. I. Masel: Catal. Rev. Sci. Eng. 28, 335 (1986).
18) A.T.S. Wee, J. Lin, A.C.H. Huan, F.C. Loh and K.L. Tan: Surf. Sci. 304,145 (1994).
19) S.K. So, R. Franchy and W. Ho: J. Chem. Phys. 91, 5701 (1989).
20) J. Randnik, F. Gimans, B. Pennemann, K. Oster and K. Wandret: Surf. Sci. 287/288, 330 (1993).
21) R.D. Ramsier, Q. Gao, H. Neergaard Waitenburg, K.-W. Lee, OW. Nooij, L. Lefferts and J.T. Yates, Jr.: Surf. Sci. 320, 209 (1994).
22) J.A. Rodriguez and J. Hrbek: J. Vac. Sci. Technol. A 12, 2140 (1994).
23) J. Stöhr and R. Jaeger: Phys. Rev. B 26, 4111(1982).

抄録

The adsorption and desorption behavior of NO on polycrystalline Rh was investigated by X-ray photoelectron spectroscopy (XPS) to elucidate the unique catalytic properties of Rh in the reduction of NO. After the adsorption of NO at room temperature, nitride and oxide which were the dissociatively adsorbed species of NO together with molecularly adsorbed NO were observed. A part of the nitride was comparatively easily desorbed by increasing NO pressure or by rising temperature. However, the oxide was not desorbed but diffused into the bulk of Rh with rising temperature. These XPS results implied the superiority of Rh for NO reduction in reducing atmospheres in spite of relatively low activity for direct decomposition of NO.

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