Ion Desorption Reaction of Surface Admolecules Induced by Synchrotron Radiation

Tetsuji SEKITANI; Kenichiro TANAKA

doi:10.1380/jsssj.19.321

放射光励起による表面吸着分子のイオン脱離反応

関谷徹司, 田中健一郎

著者情報

ジャーナルフリー

1998 年 19 巻 5 号 p. 321-327

DOI https://doi.org/10.1380/jsssj.19.321

詳細

発行日: 1998/05/10 受付日: 1997/05/19 J-STAGE公開日: 2009/08/07 受理日: 1997/05/19 早期公開日: - 改訂日: -
訂正情報
訂正日: 2009/08/07 訂正理由: - 訂正箇所: 引用文献情報訂正内容: Wrong : 1) A.P. Hitchcock: J. Electron Spectrosc. Relat. Phenom. 25, 245 (1982); ibid., 67, 1(1994).
2) J. Stöhr: “NEXAFS Spectroscopy”, Springer Ser. Surf. Sci. 25 (Springer-Verlag, Berlin, 1992).
3) W. Eberhardt, T.K. Sham, R. Karr, S. Krummacher, M. Strongin, S.L. Weng and D. Wesner: Phys. Rev. Lett. 50, 1038 (1983).
4) “Desorption Induced by Electronic Transitions, DIET I”, ed. by N.H. Tolk, M.M. Traum, J.C. Tully and T.E. Madey (Springer-Verlag, Berlin, 1983).
5) “Desorption Induced by Electronic Transitions, DIET II”, ed. by W. Brenig and D. Menzel (Springer-Verlag, Berlin, 1985).
6) “Desorption Induced by Electronic Transitions, DIET III”, ed. by R.H. Stulen and M.L. Knotek (Springer-Verlag, Berlin, 1988).
7) “Desorption Induced by Electronic Transitions, DIET IV”, ed. by G. Betz and P. Varga (Springer-Verlag, Berlin, 1990).
8) “Desorption Induced by Electronic Transitions, DIET V”, ed. by A.R. Burns, E.B. Stechel and D.R. Jennison (Springer-Verlag, Berlin, 1993).
9) T.E. Madey, D.E. Ramaker and R. Stockbauer: Ann. Rev. Phys. Chem. 35, 215 (1984).
10) V. Rehn and R.A. Rosenberg: “Synchrotron Radiation Research-Advances in Surface and Interface Science, Vol.l, Techniques”, ed. by R.Z. Bachrach (Plenum, New York, 1992) p.327.
11) D.E. Ramaker, C.T. White and J.S. Murday: J. Vac. Sci. Technol.18, 748 (1981); Phys. Lett. A 89, 211 (1982).
12) D. Coulman, A. Puschmann, U. Höfer, H.-P. Steinruck, W. Wurth, P. Feulner and D. Menzel: J. Chem. Phys. 93, 58 (1990).
13) R. Treichler, W. Wurth, W. Riedl, P. Feulner and D. Menzel: Chem.Phys.153, 259 (1991).
14) R. Treichler, W. Riedl, P. Feulner and D. Menzel: Surf. Sci. 243, 239 (1991).
15) D. Menzel, G. Rocker, H.-P. Steinruck, D. Coulman, P. A. Heimann, W. Huber, P. Zebisch and D.R. Lloyd: J. Chem. Phys. 96,1724 (1992).
16) T. Sekiguchi, H. Ikeura, K. Tanaka, K. Obi, N. Ueno and K. Honma: J. Chem. Phys. 102, 1422 (1995).
18) H. Ikeura, K. Tanaka and T. Sekiguchi: Atm. Col. Res. Jpn. 20, 97 (1994); J. Electron Spectrosc. Relat. Phenom. 80, 121 (1996); H.I. Sekiguchi, T. Sekiguchi and K. Tanaka: Phys. Rev. B 53, 12655 (1996).
19) K. Mase, M. Nagasono, S. Tanaka, M. Kamada, T. Urisu and Y. Murata: Rev. Sci. Instrum. 68,1703 (1997).
20) K. Mase, M. Nagasono, S. Tanaka, T. Urisu, E. Ikenaga, T. Sekitani and K. Tanaka: Surf. Sci. 390, 97 (1997).
21) S. Tanaka, M. Onchi and M. Nishijima: J. Chem. Phys. 91, 2712 (1989).
22) M. Yanagihara, H. Maezawa, T. Sasaki, Y. Suzuki and Y. Iguchi: KEK Report, 84-17 (1984).
23) A. Yagishita, S. Masui, T. Toyoshima, H. Maezawa and E. Shigemasa: Rev. Sci. Instrum. 63,1383 (1992).
25) D.A. Outka, J. Stohr, R.A. Madix, H.H. Rotermund, B. Hermsmeier and J. Solomon: Surf. Sci.185, 53 (1987).
26) S. Tanaka: UVSOR Activity Report 23,13 (1995).
27) G. B. Armen, T. Åberg, J.C. Levin, B. Crasemann, M. H. Chen, G.E. Ice and G.S. Brown: Phys. Rev. Lett. 54, 1142 (1985).
28) M.C.K. Tinone, K. Tanaka, J. Maruyama, N. Ueno, M. Imamura and N. Matsubayashi: J. Chem. Phys.100, 5988 (1994); M.C.K. Tinone, T. Sekitani, K. Tanaka, J. Maruyama and N. Ueno: Appl. Surf. Sci. 79/80, 89 (1994).

Right : 1) A.P. Hitchcock: J. Electron Spectrosc. Relat. Phenom. 25, 245 (1982); ibid., 67, 1(1994).
2) J. Stöhr: “NEXAFS Spectroscopy”, Springer Ser. Surf. Sci. 25 (Springer-Verlag, Berlin, 1992).
3) W. Eberhardt, T.K. Sham, R. Karr, S. Krummacher, M. Strongin, S.L. Weng and D. Wesner: Phys. Rev. Lett. 50, 1038 (1983).
4) “Desorption Induced by Electronic Transitions, DIET I”, ed. by N.H. Tolk, M.M. Traum, J.C. Tully and T.E. Madey (Springer-Verlag, Berlin, 1983).
5) “Desorption Induced by Electronic Transitions, DIET II”, ed. by W. Brenig and D. Menzel (Springer-Verlag, Berlin, 1985).
6) “Desorption Induced by Electronic Transitions, DIET III”, ed. by R.H. Stulen and M.L. Knotek (Springer-Verlag, Berlin, 1988).
7) “Desorption Induced by Electronic Transitions, DIET IV”, ed. by G. Betz and P. Varga (Springer-Verlag, Berlin, 1990).
8) “Desorption Induced by Electronic Transitions, DIET V”, ed. by A.R. Burns, E.B. Stechel and D.R. Jennison (Springer-Verlag, Berlin, 1993).
9) T.E. Madey, D.E. Ramaker and R. Stockbauer: Ann. Rev. Phys. Chem. 35, 215 (1984).
10) V. Rehn and R.A. Rosenberg: “Synchrotron Radiation Research-Advances in Surface and Interface Science, Vol.l, Techniques”, ed. by R.Z. Bachrach (Plenum, New York, 1992) p.327.
11) D.E. Ramaker, C.T. White and J.S. Murday: J. Vac. Sci. Technol.18, 748 (1981); Phys. Lett. A 89, 211 (1982).
12) D. Coulman, A. Puschmann, U. Höfer, H.-P. Steinruck, W. Wurth, P. Feulner and D. Menzel: J. Chem. Phys. 93, 58 (1990).
13) R. Treichler, W. Wurth, W. Riedl, P. Feulner and D. Menzel: Chem.Phys.153, 259 (1991).
14) R. Treichler, W. Riedl, P. Feulner and D. Menzel: Surf. Sci. 243, 239 (1991).
15) D. Menzel, G. Rocker, H.-P. Steinruck, D. Coulman, P. A. Heimann, W. Huber, P. Zebisch and D.R. Lloyd: J. Chem. Phys. 96,1724 (1992).
16) T. Sekiguchi, H. Ikeura, K. Tanaka, K. Obi, N. Ueno and K. Honma: J. Chem. Phys. 102, 1422 (1995).
18) H. Ikeura, K. Tanaka and T. Sekiguchi: Atm. Col. Res. Jpn. 20, 97 (1994); J. Electron Spectrosc. Relat. Phenom. 80, 121 (1996); H.I. Sekiguchi, T. Sekiguchi and K. Tanaka: Phys. Rev. B 53, 12655 (1996).
19) K. Mase, M. Nagasono, S. Tanaka, M. Kamada, T. Urisu and Y. Murata: Rev. Sci. Instrum. 68,1703 (1997).
20) K. Mase, M. Nagasono, S. Tanaka, T. Urisu, E. Ikenaga, T. Sekitani and K. Tanaka: Surf. Sci. 390, 97 (1997).
21) S. Tanaka, M. Onchi and M. Nishijima: J. Chem. Phys. 91, 2712 (1989).
22) M. Yanagihara, H. Maezawa, T. Sasaki, Y. Suzuki and Y. Iguchi: KEK Report, 84-17 (1984).
23) A. Yagishita, S. Masui, T. Toyoshima, H. Maezawa and E. Shigemasa: Rev. Sci. Instrum. 63,1383 (1992).
25) D.A. Outka, J. Stohr, R.A. Madix, H.H. Rotermund, B. Hermsmeier and J. Solomon: Surf. Sci.185, 53 (1987).
26) S. Tanaka: UVSOR Activity Report 23,13 (1995).
27) G. B. Armen, T. Åberg, J.C. Levin, B. Crasemann, M. H. Chen, G.E. Ice and G.S. Brown: Phys. Rev. Lett. 54, 1142 (1985).
28) M.C.K. Tinone, K. Tanaka, J. Maruyama, N. Ueno, M. Imamura and N. Matsubayashi: J. Chem. Phys.100, 5988 (1994); M.C.K. Tinone, T. Sekitani, K. Tanaka, J. Maruyama and N. Ueno: Appl. Surf. Sci. 79/80, 89 (1994).

抄録

Studies of surface photochemical reactions induced by core excitation have developed with the advance of synchrotron radiation technique over a range extending from vacuum ultraviolet to soft X-ray. Studies of the photon stimulated ion desorption (PSID) have been carried out mainly on the basis of the initial excitation energy dependence of the desorption yield. In particular, site-specific reactions have been found in PSID following core electron excitation. This is very interesting from the viewpoint of the control of chemical reactions using monoenergetic photo-excitation. The Auger stimulated ion desorption (ASID) mechanism is widely proposed as a model of PSID. As the Auger final state is directly related to the ion desorption in this model to elucidate the PSID mechanism, it is essential to get the information about the Auger final state. In this article, we have described about PSID of formic acid induced by carbon core excitation using ion TOF method and about PSID of condensed H2O induced by oxygen core excitation using Auger electronphotoion coincidence (AEPICO) method.

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